Napoli will bid to boost their chances of making progress in the 2025-26 Champions League when they visit PSV Eindhoven on October 21.The Serie A giants suffered a defeat in their opening game at Manc...
Napoli will bid to boost their chances of making progress in the 2025-26 Champions League when they visit PSV Eindhoven on October 21.
The Serie A giants suffered a defeat in their opening game at Manchester City, but bounced back with a hard-fought victory over Sporting SP in their second outing.
On-loan striker Rasmus Hojlund scored twice against the Primeira Liga outfit and will fancy his chances of adding to his tally as the competition progresses.
The Champions League betting odds at Spreadex Sports favour Hojlund to top the scoring charts for Napoli in the Champions League, predicting he will bag at least five goals this season.
The Denmark international will be eager to outstrip that prediction and help Napoli make a deep run in UEFA’s top club competition.
Read on as we look at the latest betting for the Champions League, before assessing how Napoli are likely to fare in the rest of the opening phase.
Champions League 2025-26 – Betting
The latest outright odds for the 2025-26 Champions League are as follows:
- Paris Saint-Germain – 11/2
- Barcelona – 11/2
- Arsenal – 6/1
- Liverpool – 13/2
- Real Madrid – 9/1
- Bayern Munich – 9/1
- Manchester City – 10/1
- Chelsea – 16/1
- Inter Milan – 25/1
- Napoli – 28/1
- Newcastle United – 28/1
- Tottenham Hotspur – 33/1
- Atletico Madrid – 40/1
- Juventus – 40/1
- Borussia Dortmund – 50/1
- Atalanta – 66/1
- Bayer Leverkusen – 66/1
- Eintracht Frankfurt – 100/1
- Monaco – 100/1
- Marseille – 125/1
- Villarreal – 125/1
- Athletic Club – 150/1
- Sporting CP – 200/1
- Benfica – 200/1
- PSV Eindhoven – 200/1
- Club Brugge – 200/1
- Galatasaray – 200/1
- Union Saint Gilloise – 250/1
- Ajax – 250/1
- Olympiacos – 250/1
- FC Copenhagen – 350/1
- Bodo/Glimt – 500/1
- Qarabag – 500/1
- Pafos – 1000/1
- Slavia Prague – 1000/1
- Kairat Almaty – 2000/1
Champions League 2025-26 – Matchday 3 Fixtures
Tuesday, October 21
- Barcelona vs Olympiacos
- Kairat Almaty vs Pafos
- Arsenal vs Atletico Madrid
- Bayer Leverkusen vs Paris Saint-Germain
- FC Copenhagen vs Borussia Dortmund
- Newcastle United vs Benfica
- PSV Eindhoven vs Napoli
- Union Saint-Gilloise vs Inter Milan
- Villarreal vs Manchester City
Wednesday, October 22
- Athletic Club vs Qarabag
- Galatasaray vs Bodo/Glimt
- Monaco vs Tottenham Hotspur
- Atalanta vs Slavia Prague
- Chelsea vs Ajax
- Eintracht Frankfurt vs Liverpool
- Bayern Munich vs Club Brugge
- Real Madrid vs Juventus
- Sporting CP vs Marseille
Champions League 2025-26 – Hojlund eager to continue his good form
Hojlund joined the reigning Serie A champions from Manchester United on loan for the season, and he has settled in well with the club.
After bagging four goals in six appearances across all competitions, the 22-year-old has started to show why the Red Devils may have slipped up by letting him go.
The Danish international aimed a dig at United in a recent interview, claiming he has rediscovered his touch because he is now playing for a ‘good football team’.
Hojlund clearly feels he has a point to prove after failing to live up to expectations at United, which could work in Napoli’s favour this season.
Odds of 28/1 to win the Champions League highlight the size of the task they face, but it would be foolish to completely dismiss their chances.
NAPLES, ITALY – OCTOBER 05: Antonio Conte SSC Napoli head coach during the Serie A match between SSC Napoli and Genoa CFC at Stadio Diego Armando Maradona on October 05, 2025 in Naples, Italy. (Photo by Francesco Pecoraro/Getty Images)
Manager Antonio Conte is a serial winner and his talented squad have the ability to match the so-called big guns in this competition.
While PSV will be no pushovers on Matchday 3, Napoli are perfectly capable of going to the Netherlands and securing a positive result.
Subsequent home fixtures against Eintracht Frankfurt and Qarabag offer Napoli the chance to put themselves into a healthy position in the league phase.
Visits to Benfica and FC Copenhagen will be challenging, while the final home game against Chelsea is an extremely tough test.
However, securing a top-eight finish is an achievable aim for Napoli, and they look a good bet to get the job done with Hojlund in their ranks.
Category: General Sports
